| Date | Home | Away | Result |
|---|---|---|---|
| 14/01/25 20:00 | CF Ourense | FC Valencia | 0-2 |
| 15/01/25 18:30 | UD Almeria | CD Leganes | 2-3 |
| 15/01/25 18:30 | CF Pontevedra | FC Getafe | 0-1 |
| 15/01/25 20:00 | FC Barcelona | Real Betis Sevilla | 5-1 |
| 15/01/25 20:30 | FC Elche | Atletico Madrid | 0-4 |
| 16/01/25 18:30 | Athletic Bilbao | CA Osasuna | 2-3 |
| 16/01/25 18:30 | Real Sociedad | Rayo Vallecano | 3-1 |
| 16/01/25 20:30 | Real Madrid | Celta Vigo | 5-2a.e.t |